Experimental Electrochemical Potentials of Nickel Complexes

Lin, Q.; Dawson, G.; Diao, T.
Synlett 2021, 32, 1606-1620.

(Invited contribution)

Monovalent Nickel-Mediated Radical Formation: A Concerted Halogen-Atom Dissociation Pathway Determined by Electroanalytical Studies

Lin, Q.; Fu, Y.; Liu, P.; Diao, T.
J. Am. Chem. Soc. 2021, 143, 14196-14206.

Insertion of CO2 Mediated by a (Xantphos)Ni(I)–Alkyl Species

Diccianni, J. B.; Hu, T. H.; Diao, T.
Angew. Chem. Int. Ed. 2019, 58, 13865-13868.

Mechanistic Characterization of (Xantphos)Ni(I)-Mediated Alkyl Bromide Activation: Oxidative Addition, Electron Transfer, or Halogen-Atom-Abstraction

Diccianni, J. B.; Katigbak, J.; Hu, C.; Diao, T.
J. Am. Chem. Soc. 2019, 141, 4, 1788-1796

Bimetallic, High-Valent Nickel Complexes: Ni–Ni Bonds in Aryl–Halogen Bond Formation

Diccianni, J. B.; Hu, C.; Diao, T.
Angew. Chem. Int. Ed. 2017, 56, 3635-3639.

Structure and Isotope Effects of the β-H Agostic (α-Diimine)Nickel Cation as a Polymerization Intermediate

Xu, H.; White, P. B.; Hu, C.; Diao, T.,
Angew. Chem. Int. Ed. 2017, 56, 1535-1538.

N−N Bond Forming Reductive Elimination via a Mixed-Valent Nickel(II)-Nickel(III) Intermediate

Diccianni, J. B.; Hu, C.; Diao, T.
Angew. Chem. Int. Ed. 2016, 55, 7534-7538.

Bimetallic C–C Bond-Forming Reductive Elimination from Nickel 

Xu, H.; Diccianni, J. B.; Katigbak, J.; Hu, C.; Zhang, Y.; Diao, T.
J. Am. Chem. Soc. 2016, 138, 4779-4786.